Bis{2-[(2,4,6-trimethylphenyl)iminomethyl]pyrrol-1-ido}palladium(II)
Acta crystallographica. Section E, structure reports online. Bd. 69. H. 2. Copenhagen: Munksgaard 2013 S. 96
Erscheinungsjahr: 2013
ISBN/ISSN: 1600-5368
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1107/S1600536813000573
Inhaltszusammenfassung
The title compound, [Pd(C14H15N2)2], is a square-planar palladium complex composed of two deprotonated pyrrole- 2-carbaldimine ligands coordinating a central PdII atom. In the crystal, three crystallographically independent complex molecules are observed, one of which is located in a general position, whereas the PdII atoms of the other molecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three molecules show dihedral angles of 87...The title compound, [Pd(C14H15N2)2], is a square-planar palladium complex composed of two deprotonated pyrrole- 2-carbaldimine ligands coordinating a central PdII atom. In the crystal, three crystallographically independent complex molecules are observed, one of which is located in a general position, whereas the PdII atoms of the other molecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three molecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)? with respect to the corresponding PdN4 plane.» weiterlesen» einklappen
Klassifikation
DFG Fachgebiet:
Molekülchemie
DDC Sachgruppe:
Zeitschriften, fortlaufende Sammelwerke
