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Hydrogen induced attack of Al2O3-SiO2 Refractories: Application of SEM Techniques and Thermodynamics

European Centre for Refractories (ECREF) (Hrsg). Proceedings 18th Unified International Technical Conference on Refractories (UNITECR): Biennial Worldwide Congress on Refractories. Höhr-Grenzhausen. 2023 S. 889

Erscheinungsjahr: 2023

Publikationstyp: Diverses (Konferenzband)

Sprache: Englisch

GeprüftBibliothek

Inhaltszusammenfassung


In order to reduce CO2 emissions, a change is currently taking place within the steel industry towards hydrogen-based steel production. For this purpose, the requirement profile for the refractory materials is thus being extended to include a resistance to hydrogen. The aim of this poster is to characterize the structural changes respectively the corrosion mechanism occurring in an Al2O3-SiO2 refractory material, which experienced a hydrogen induced attack. SEM techniques were applied and t...In order to reduce CO2 emissions, a change is currently taking place within the steel industry towards hydrogen-based steel production. For this purpose, the requirement profile for the refractory materials is thus being extended to include a resistance to hydrogen. The aim of this poster is to characterize the structural changes respectively the corrosion mechanism occurring in an Al2O3-SiO2 refractory material, which experienced a hydrogen induced attack. SEM techniques were applied and the results were verified with thermochemical calculations. First, a corrosion test was conducted. Therefore, the refractory material was exposed to 100 % H2 for 200 h at 1400°C. Subsequently, an elemental analysis by SEM of the hydrogen-induced corrosion zone of the refractory was performed. The corrosion mechanism was described by thermodynamic modeling using the software FactSage» weiterlesen» einklappen

Autoren


Henn, Isabelle (Autor)
Sax, Almuth (Autor)

Klassifikation


DFG Fachgebiet:
Materialwissenschaft

DDC Sachgruppe:
Ingenieurwissenschaften

Verknüpfte Personen