Hydrogen induced attack of Al2O3-SiO2 Refractories: Application of SEM Techniques and Thermodynamics
European Centre for Refractories (ECREF) (Hrsg). Proceedings 18th Unified International Technical Conference on Refractories (UNITECR): Biennial Worldwide Congress on Refractories. Höhr-Grenzhausen. 2023 S. 889
Erscheinungsjahr: 2023
Publikationstyp: Diverses (Konferenzband)
Sprache: Englisch
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Inhaltszusammenfassung
In order to reduce CO2 emissions, a change is currently taking place within the steel industry towards hydrogen-based steel production. For this purpose, the requirement profile for the refractory materials is thus being extended to include a resistance to hydrogen. The aim of this poster is to characterize the structural changes respectively the corrosion mechanism occurring in an Al2O3-SiO2 refractory material, which experienced a hydrogen induced attack. SEM techniques were applied and t...In order to reduce CO2 emissions, a change is currently taking place within the steel industry towards hydrogen-based steel production. For this purpose, the requirement profile for the refractory materials is thus being extended to include a resistance to hydrogen. The aim of this poster is to characterize the structural changes respectively the corrosion mechanism occurring in an Al2O3-SiO2 refractory material, which experienced a hydrogen induced attack. SEM techniques were applied and the results were verified with thermochemical calculations. First, a corrosion test was conducted. Therefore, the refractory material was exposed to 100 % H2 for 200 h at 1400°C. Subsequently, an elemental analysis by SEM of the hydrogen-induced corrosion zone of the refractory was performed. The corrosion mechanism was described by thermodynamic modeling using the software FactSage» weiterlesen» einklappen
Klassifikation
DFG Fachgebiet:
Materialwissenschaft
DDC Sachgruppe:
Ingenieurwissenschaften