Cobalt-catalyzed aerobic oxidation of (E)- and (Z)-bishomoallylic alcohols
TETRAHEDRON LETTERS. Bd. 50. H. 8. 2009 S. 960 - 962
Erscheinungsjahr: 2009
ISBN/ISSN: 0040-4039
Publikationstyp: Zeitschriftenaufsatz
Doi/URN: 10.1016/j.tetlet.2008.12.040
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Inhaltszusammenfassung
Stereoselectivity for (5-phenyltetrahydrofur-2-yl)alkan-1-ol formation (cis:trans < 1:99) from 5-methyl- and 5-phenyl-substituted 1-phenylpent-4-en-1-ols via cobalt-catalyzed aerobic oxidation was independent of the olefinic pi-bond configuration of the substrates. (C) 2008 Elsevier Ltd. All rights reserved.