Inhaltszusammenfassung

The performance of a novel portable, tunable diode laser, resonant photoacoustic (TDL-PA) analyzer developed for field measurements of CH4 was compared to a commonly applied offline gas chromatographic (GC) method. This comparative study was realized under normal field conditions parallel to long-term weekly GC monitoring of four different soil types with very different methane budgets. The method used for gas-exchange measurements was the well-known closed-chamber technique. The TDL-PA analy...The performance of a novel portable, tunable diode laser, resonant photoacoustic (TDL-PA) analyzer developed for field measurements of CH4 was compared to a commonly applied offline gas chromatographic (GC) method. This comparative study was realized under normal field conditions parallel to long-term weekly GC monitoring of four different soil types with very different methane budgets. The method used for gas-exchange measurements was the well-known closed-chamber technique. The TDL-PA analyzer detects methane at 1650.957 nm [R (5) line of the 2 v 3 band], guaranteeing high precision without the need for correction procedures. The two techniques correlated well (R-2 = 0.988) over the entire concentration range (0.15-33 ppmv CH4) tested at highly varying flux rates between-30 and -12 ppbv CH4 min(-1) for uptakes and between 2.5 and 362 ppbv CH4 min(-1) for emissions. The two analyzers proved to be interchangeable, leaving the online advantages to the TDL-PA. A suitable CH4 online GC solution for chamber measurement is not available as a portable system. Additionally, the data sampling rate of 2 Hz enables a direct coupling to other infrared gas analyzers with the high time resolution commonly required to determine plant CO2 assimilation rates or soil respiration rates. » weiterlesen» einklappen

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