STABLE BIS(ALKYNYL)TITANOCENE COMPLEXES OF FECL2 AND CUCL
JOURNAL OF ORGANOMETALLIC CHEMISTRY. Bd. 409. H. 3. 1991 S. C7 - C11
Erscheinungsjahr: 1991
ISBN/ISSN: 0022-328X
Publikationstyp: Zeitschriftenaufsatz
Doi/URN: 10.1016/0022-328X(91)80027-H
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Inhaltszusammenfassung
The application of (eta-5-C5H4SiMe3)2Ti(C=C-SiMe3)2 as an organometallic bidentate chelate ligand for MCl 2 building blocks (M = Fe, Co, Ni) is discussed. Reaction of the organometallic substituted alkyne Me3Si-C=C-(eta-5-C5H4SiMe3)2Ti-C=C-SiMe3, I, with FeCl2 affords in high yields thc dinuclear complex {(eta-5-C5H4SiMe3)2Ti(C= C-SiMe3)2}FeCl2, II. The identity of compound II is confirmed by analytical and spectroscopic data as well as by an X-ray diffraction study. Structural data for L2Ti(...The application of (eta-5-C5H4SiMe3)2Ti(C=C-SiMe3)2 as an organometallic bidentate chelate ligand for MCl 2 building blocks (M = Fe, Co, Ni) is discussed. Reaction of the organometallic substituted alkyne Me3Si-C=C-(eta-5-C5H4SiMe3)2Ti-C=C-SiMe3, I, with FeCl2 affords in high yields thc dinuclear complex {(eta-5-C5H4SiMe3)2Ti(C= C-SiMe3)2}FeCl2, II. The identity of compound II is confirmed by analytical and spectroscopic data as well as by an X-ray diffraction study. Structural data for L2Ti(C=C-SiMe3)2, I, {L2Ti(C=C-SiMe3)2}FeCl2, II, and (L2Ti(C=C-SiMe3)2}CuCl, III, (L = eta-5 C5H4SiMe3) are discussed. » weiterlesen» einklappen