Controlled synthesis of (1,3-ᵗBu₂-C₅H₃)₂TiCl₂ and (1,3-ᵗBu₂-C₅H₃)TiCl₃⋅ Crystal structure and reactions of (1,3-ᵗBu₂-C₅H₃)TiCl₃
Journal of Organometallic Chemistry. Bd. 433. H. 3. Amsterdam: Elsevier 1992 S. 253 - 259
Erscheinungsjahr: 1992
ISBN/ISSN: 1872-8561
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1016/0022-328X(92)80151-M
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Inhaltszusammenfassung
The compounds (1,3-tBu2C5H3)2TiCl2, (I) and (1,3-tBu2C5H3)TiCl3 (II) were prepared in good yields from TiCl4 and (1,3-tBu2-C5H3)Li. Reactions of II with methanol, ethane-1,2-diol, sodium oxalate, and 2-pyrazine carboxylic acid afforded various organotitanium complexes. The crystal structure of II was determined.
Autoren
Jibril, Ibrahim (Autor)
Abu-Orabi, Sultan (Autor)
Klaib, Sami A. (Autor)
Huttner, Gottfried (Autor)
