Tetrakis(tert⁻butyl isocyanide⁻2κC)dichloro⁻1κCl,3κCl⁻di⁻μ⁻cyano⁻1κN:2κC;2κC:3κN⁻bis[1,3(η⁴)⁻cycloocta⁻1,5⁻diene]dirhodium(I)ruthenium(II)
Acta Crystallographica Section E : Crystallographic Communications. Bd. E61. H. 10. Chester: International Union of Crystallography 2005 S. m2130 - m2132
Erscheinungsjahr: 2005
ISBN/ISSN: 2056-9890
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1107/S1600536805030461
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Inhaltszusammenfassung
The title compound, [ Rh2Ru( CN) Cl-2(2)( C8H12)(2)( C5H9N)(4)], was obtained from the reaction of the chloro( 1,5-cyclooctadiene) rhodium( I) dimer with trans-dicyanotetra( tert-butyl isocyanide) ruthenium( II) by cleavage of the chloro bridges in the dimeric rhodium starting complex. The molecular structure shows the Ru atom in a nearly ideal octahedral coordination geometry, whereas the Rh atoms are situated in square-planar ligand environments. The central ruthenium ion is located on a cr...The title compound, [ Rh2Ru( CN) Cl-2(2)( C8H12)(2)( C5H9N)(4)], was obtained from the reaction of the chloro( 1,5-cyclooctadiene) rhodium( I) dimer with trans-dicyanotetra( tert-butyl isocyanide) ruthenium( II) by cleavage of the chloro bridges in the dimeric rhodium starting complex. The molecular structure shows the Ru atom in a nearly ideal octahedral coordination geometry, whereas the Rh atoms are situated in square-planar ligand environments. The central ruthenium ion is located on a crystallographic twofold axis. The crystal structure is realized by infinite chains of the trinuclear complex units which are connected by C - H (...) Cl interactions. These chains are further linked by another C - H (...) Cl interaction to produce the observed three-dimensional structure. » weiterlesen» einklappen
