Bis[N,N'-bis(trimethylsilyl)benzamidinato]diethylhafnium(IV)
Acta Crystallographica Section E : Crystallographic Communications. Bd. E62. H. 3. Chester: International Union of Crystallography 2006 S. m568 - m570
Erscheinungsjahr: 2006
ISBN/ISSN: 2056-9890
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1107/S1600536806005721
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Inhaltszusammenfassung
In the title compound, [Hf(C2H5)(2)(C13H23N2Si2)(2)], the Hf atom is coordinated by two ethyl groups and two bis(tri-methylsilyl) benzamidinate (siam) ligands binding in a bidentate coordination mode via their N-donor atoms. The coordination around hafnium is best described as slightly distorted tetrahedral if the siam ligands are represented by their centroids.
