Di-µ-chlorido-bis{[(3,4-η)-2,5-dimethylhex-3-yne-2,5-diol]copper(I)}
Acta Crystallographica Section E : Crystallographic Communications. Bd. E63. H. 4. Chester: International Union of Crystallography 2007 S. m968 - m970
Erscheinungsjahr: 2007
ISBN/ISSN: 2056-9890
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1107/S1600536807009580
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Inhaltszusammenfassung
The title compound, [Cu2Cl2(C8H14O2)(2)], exhibits a non-planar four- membered Cu2Cl2 ring, with one alkyne ligand coordinated to each Cu atom. Due to the presence of the Cl bridges as potential hydrogen-bond acceptor sites, one of the hydroxy substituents is engaged in an intramolecular hydrogen bond, whereas the remaining three OH groups form intermolecular interactions which sustain the supramolecular structure.
