Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
Acta Crystallographica Section E : Crystallographic Communications. Bd. E64. H. 8. Chester: International Union of Crystallography 2008 S. M1000 - U287
Erscheinungsjahr: 2008
ISBN/ISSN: 2056-9890
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1107/S1600536808020138
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Inhaltszusammenfassung
The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent molecules per asymmetric unit. The central Ni atom of each independent molecule has a nearly perfect tetrahedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the first structurally characterized Ni(0) compound with a mixed CO/RNC coordination.
