Spectroscopic and theoretical study of asymmetric 1,1'-diaminoferrocene conjugates of alpha-amino acids
Organometallics. Bd. 27. H. 7. 2008 S. 1447 - 1453
Erscheinungsjahr: 2008
ISBN/ISSN: 0276-7333
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1021/om701222e
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Inhaltszusammenfassung
The synthesis and characterization of asymmetric 1,1'-diaminoferroceneconjugates of alpha-amino acids Boe-AA-NH-Fn-NH-Ac [AA = Gly (10), Ala(11), D-Ala (12), Val (13), Fn = 1,1'-ferrocenediyl] is reported. Theconformational preferences of these organometallic peptidomimetics insolution are determined experimentally by circular dichroismspectroscopy, IR spectroscopy, and NMR spectroscopy and corroboratedtheoretically by DFT calculations.
Autoren
Djakovic, S. (Autor)
Siebler, Daniel (Autor)
Semencic, M. C. (Autor)
Rapic, V. (Autor)
Klassifikation
DDC Sachgruppe:
Chemie
