Inhaltszusammenfassung

This overview highlights recent progress in the field of selectiveconstruction of linear, oligonuclear transition-metal complexes byusing solid-phase synthesis procedures. Two general protocols have beenidentified: formation of coordinative bonds between metal centres andbridging ligands and formation of covalent bonds between preformedkinetically inert transition-metal-containing building blocks in thechain growth step. Currently available suitable building blocks for thesecond approach are ...This overview highlights recent progress in the field of selectiveconstruction of linear, oligonuclear transition-metal complexes byusing solid-phase synthesis procedures. Two general protocols have beenidentified: formation of coordinative bonds between metal centres andbridging ligands and formation of covalent bonds between preformedkinetically inert transition-metal-containing building blocks in thechain growth step. Currently available suitable building blocks for thesecond approach are based on ferrocene units,bis(terpyridine)-ruthenium(II) moieties or metal porphyrins.» weiterlesen» einklappen

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Klassifikation

DDC Sachgruppe:
Chemie